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The photochemistry of a diepoxy ketone

thesis
posted on 08.02.2017, 04:10 authored by Schneider, Diana Sonja
In dilute ethanol or tertiary butanol solutions irradiated with light of wavelength 300 nm, 1:1', 3:4-diepoxy-1-methyl-2- tetralone (I) was found to rearrange to the phenols (III) and (XIX) and to the pyrone (XXI). The identities of (XIX) and (XXI) were confirmed by synthesis whilst the identity of (III) was confirmed by comparing its properties with those of an authentic sample. Possible rearrangement mechanisms leading to the formation of these products are described.

History

Campus location

Australia

Principal supervisor

F. W. Eastwood

Year of Award

1970

Department, School or Centre

Monash University. Faculty of Science

Course

Master of Science

Degree Type

MASTERS

Faculty

Faculty of Science

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