The photochemistry of a diepoxy ketone Schneider, Diana Sonja 10.4225/03/589a9a33c4cd8 https://bridges.monash.edu/articles/thesis/The_photochemistry_of_a_diepoxy_ketone/4628680 In dilute ethanol or tertiary butanol solutions irradiated with light of wavelength 300 nm, 1:1', 3:4-diepoxy-1-methyl-2- tetralone (I) was found to rearrange to the phenols (III) and (XIX) and to the pyrone (XXI). The identities of (XIX) and (XXI) were confirmed by synthesis whilst the identity of (III) was confirmed by comparing its properties with those of an authentic sample. Possible rearrangement mechanisms leading to the formation of these products are described. 2017-02-08 04:10:26 Photochemistry 1959.1/1281623 ethesis-20160901-115615 monash:173099 1970 thesis(masters) Epoxy ketone Restricted access