The photochemistry of a diepoxy ketone
Schneider, Diana Sonja
10.4225/03/589a9a33c4cd8
https://bridges.monash.edu/articles/thesis/The_photochemistry_of_a_diepoxy_ketone/4628680
In dilute ethanol or tertiary butanol solutions irradiated
with light of wavelength 300 nm, 1:1', 3:4-diepoxy-1-methyl-2-
tetralone (I) was found to rearrange to the phenols (III) and (XIX) and
to the pyrone (XXI). The identities of (XIX) and (XXI) were confirmed
by synthesis whilst the identity of (III) was confirmed by comparing
its properties with those of an authentic sample. Possible
rearrangement mechanisms leading to the formation of these products
are described.
2017-02-08 04:10:26
Photochemistry
1959.1/1281623
ethesis-20160901-115615
monash:173099
1970
thesis(masters)
Epoxy ketone
Restricted access